User blog comment:OnePiece-Kaizokudan/Porchemy off-screen death/@comment-3213092-20111123004826/@comment-972068-20111123005336

The face would be the eyes, nose, mouth, chin, and everything inbetween. The head is everything above the neck. So yeah. Shooting the face would also be shooting the head. But shooting the head might not necessarily be shooting the face.