Whisky Peak Arc

The Whiskey Peak arc is the eighth story arc of the anime and manga series One Piece. It is the second in the Baroque Works Saga. Whiskey Peak (called Misty Peak in the English dub) is the first island the Straw Hat Pirates encounter on The Grand Line. With a Log Pose (Eternal Compass in the English version) now in hand, the Straw Hats are directed toward Whiskey Peak: a town that welcomes pirates with open arms and treats them like celebrities. Obviously, it's too good to be true and the island's residents soon show their true colors. What's more, an even bigger surprise is about to be uncovered.

Summary
The arc begins with the crew out in the ocean on the starting leg of the Grand Line and quickly are introduced to the abnormality of the place as they experience first hand the ever changing weather, the shifting of the wind and the tides constantly keeping the crew (save for Zoro who slept through the whole thing) on their toes. Eventually the weather stabilizes and the crew spot an island on the horizon, the cactus town Whiskey Peak. Once there, Mr. 9 and Miss Wednesday thank the crew and jump ship much to the crew's confusion. Since the log pose needs time to reset, the crew have no choice but to dock at the mysterious island. Much to their surprise the resident welcome them as if they were heroes. Soon they meet the town's leader, Igarappoi who treats them with a party. The crew quickly take to the place eating, drinking, and flirting (in Sanji and Ussop's case) themselves silly into the night till eventually they all fall asleep.

However Igarappoi, as well as a few other operatives in disguise, turn out to be agents of the elusive Baroque Works criminal syndicate, but both Zoro and Nami knew something was wrong and stayed awake, thwarting their surprise attack. This syndicate operates only with the assignments that are delegated to its agents by the leader, who, like every other member higher than it's latter, remained secret and anonymous. When the town hiding bounty hunters (aka. Millions) are discovered, they hunt and attempt to murder Zoro who, without much effort, picks them off little by little, leaving an anxious Mr. 8, Mr. 9, Miss Monday and Miss Wednesday to be dealt with.

Soon after, Mr. 5 and his lady partner Miss Valentine arrive, but were not present to aid the other, less capable agents of the organization. They reveal that the leader of Baroque Works (Mr.0) has discovered a spy, who has somehow successfully infiltrated its ranks, and that they've been sent to dispatch them. The spies are none other than Igaram (Mr.8, who used the alias Igarappoi as the town's leader) and Princess Nefertari Vivi (Ms. Wednesday) of the Arabasta kingdom. Mr. 9 and Ms. Monday, despite being rather unaware of the situation to their own admission, decide to hold off the Mr. 5 pair so that Vivi can escape but are quickly defeated.

In a twist of fate, the pirates that Vivi was meant to kill in her role as a double-agent are now her protectors, when Igaram promises Nami 100,000,000 to ensure her safety back to Arabasta. When Zoro comes to Vivi's rescue, however, Luffy arrives at the scene and attacks him, under the assumption Zoro killed everyone in the town because they didn't make his favorite food. After fighting for a bit, they unintentionally defeat the Mr. 5 pair and stop fighting when they are hit by Nami.

At this point, Vivi explains that her kingdom was being ruined by a civil war started by Baroque Works, and if she can confront the rebel army with the information on the true cause of the war, she can end it. The leader of Baroque Works, according to her, wants to take over Arabasta and turn it into an "ideal nation" ruled by him, and she reveals the name of the leader--Crocodile of the Shichibukai. Unfortunately, by revealing his name, Luffy, Zoro, and Nami are added to the Baroque Works hitlist by the nearby Mr. 13, causing Nami to throttle her.

Afterwards, Igaram appears dressed as Vivi and explains that he will act as a decoy. He departs from Whiskey Peak, only to have his ship be blown up as soon as he leaves, apparently killing him. The Straw Hats and Vivi run to the Going Merry only to find Miss Allsunday, the highest ranking female Baroque Works agent, waiting for them. As it turns out, she was the one who let Vivi find out the boss's identity, yet she was also the one who revealed that she and Igaram were double-agents and blew up the ship, so the crew is not sure whose side she's on. Ms. Allsunday gives them an Eternal Pose (a permanent Log Pose) to Nanimonai Island, which is supposedly very close to Arabasta, but Luffy destroys it, claiming that she doesn't decide their course. As Ms. Allsunday leaves, the crew leave for Little Garden, the next island of the Grand Line.

Story Impact
Zoro's victory over the 100 Bounty hunters in this arc would later cause the World Government to issue his first bounty after the the events of the Arabasta arc.