Episode 94

Short Summary
While in Nanohana, the Straw Hats encounter Smoker and Tashigi. A powerful pirate named Portgas D. Ace appears, and is revealed to be Luffy's older brother.

Characters in Order of Appearance

 * Portgas D. Ace
 * Tony Tony Chopper
 * Usopp
 * Nami
 * Roronoa Zoro
 * Tashigi
 * Smoker
 * Monkey D. Luffy
 * Yoshimoto
 * Nefertari Vivi
 * Sanji
 * Carue

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Gōketsu-tachi no Saikai! Yatsu no Na ha Hiken no Ace